Vista - Can one put offline files at a specific location?

I would like to make certain folders available offline, but at the same
time I would like to put them in specific local locations, i.e. not
under the name \\<remote-system>\<remote-path> but e.g. somehwere under
e.g. C:\Users\<user>\Documents.

Since that's probably not possible, can one use Junctions to point into
offline-folders? Could I e.g. have a Junction
C:\Users\mmo\Documents\RemotePics that is actually an offline folder
that sits on \\<remote-system>\<pictureshare>?

Michael